Sodium Safety: Action and Reaction
1979 film, with transcript
Catalog description: A liquid metal sodium safety film made as part of the Clinch River Breeder Reactor Program. This is for training operators of sodium-cooled nuclear reactors.
This is film 7479944 in our catalog.
Show transcript
| 00:30 | The fast flux test facility, a test reactor operating at high core temperatures. |
| 00:47 | At the FFTF, sodium is used as a coolant to carry reactor heat. |
| 00:51 | There are several reasons sodium has been selected. |
| 00:55 | One is that it doesn't slow down the fast neutrons in the fission process as much as |
| 00:58 | in water-cooled reactors. Another is that sodium has a high boiling point, enabling it to be used |
| 01:05 | at essentially atmospheric pressure. In the event of a leak then, the sodium would not be driven out |
| 01:10 | as it would in a pressurized reactor. The high temperature at which sodium can be operated will |
| 01:16 | result in efficient electricity generation in future liquid metal-cooled reactors. Additionally, |
| 01:22 | sodium has excellent heat transfer properties, which would allow the use of a more compact |
| 01:27 | reactor core. As you know, there are some potential hazards associated with sodium. |
| 01:33 | Your awareness of these hazards is an important part of the assurance that there will be no |
| 01:38 | incidents. One concern is the possibility of radioactive contamination. Contamination and |
| 01:45 | activation of the sodium can result from the high neutron density within the reactor itself. |
| 01:50 | Because of this condition in the reactor, the contaminated sodium will be limited to the |
| 01:54 | primary loop, only the sodium's heat will be transferred. This is done by an intermediate |
| 02:00 | heat exchanger to a secondary loop of sodium which is not radioactive. After passing through |
| 02:05 | the secondary loop, the heat will be released to the atmosphere through these heat exchangers. |
| 02:14 | Sodium was in solid form when it arrived in tank cars at FFTF. In this form, it was not |
| 02:19 | radioactive. Later it was melted in the tank cars through heating, then transferred to the loops. |
| 02:27 | Warning signs and barriers are placed to indicate the location of sodium in the FFTF. |
| 02:32 | Be sure to observe and obey these signs. And before you enter any area marked as restricted, |
| 02:38 | be sure you are authorized to enter. If you are in doubt, check with the control room first. |
| 02:44 | Normal operating temperatures in the FFTF range between 400 and 1000 degrees Fahrenheit. |
| 02:51 | Since sodium can spontaneously ignite in air at temperatures as low as 238 degrees Fahrenheit, |
| 02:57 | we have designed several features into the plant to moderate the effects of a sodium fire. |
| 03:02 | For example, pressure in the system itself is so low, sodium leaks would usually be very small. |
| 03:09 | small. Primary sodium systems will be in steel-lined cells which are inerted with nitrogen. Because |
| 03:16 | it normally won't contact an oxygen atmosphere, any leakage of primary sodium would not ignite. |
| 03:22 | It would flow to the floor and solidify, where it could be easily cleaned up. Secondary sodium |
| 03:28 | systems will be in cells which can be flooded with nitrogen to extinguish sodium fires. |
| 03:39 | Here at a test site near the 300 area, 20 pounds of sodium is heated to its ignition point. |
| 03:50 | The resulting fire is relatively low-lying and gives off little adjacent heat. |
| 04:00 | A gasoline fire, by comparison, burns much hotter, sending flames several feet into the air. |
| 04:06 | Although a sodium fire appears tame, it cannot be extinguished in the usual way. |
| 04:13 | Here's why. |
| 04:14 | When sodium combines with water, it forms sodium hydroxide and hydrogen. |
| 04:19 | The hydrogen is ignited by the heat of the burning sodium. |
| 04:23 | So, rather than extinguishing it, water would feed the flames, |
| 04:26 | causing a more serious fire, and under certain conditions, explosions can result. |
| 04:36 | Water, then, cannot be used to fight a sodium fire. |
| 04:42 | Carbon dioxide extinguishers are also ineffective because if dry ice, which normally forms on |
| 04:48 | the nozzle, drops in the sodium, an explosion results. |
| 04:54 | Therefore, neither water-filled nor CO2 extinguishers should be found near a sodium system. |
| 05:01 | liquid metal fires at FFTF will be fought with nitrogen or NACs. NACs is a fluidized |
| 05:08 | form of sodium carbonate. This compound will not interact with sodium, so it is an effective |
| 05:14 | extinguishing for sodium fires. NACs extinguishers have a star marking and are yellow. They are |
| 05:21 | also labeled NACs. When NACs is sprayed over a sodium fire, it breaks the fire's chain |
| 05:28 | It breaks the fire's chain reaction by removing one of the vital links, oxygen. |
| 05:34 | As you see, a small sodium fire is easily extinguished by coating the surface with NACs. |
| 05:44 | After the sodium is allowed to cool, it solidifies and can then be removed. |
| 05:53 | This special gear is an added protection for personnel working in an area where there is |
| 05:57 | a sodium leak potential. It includes protective clothing, a hard hat with face shield, and |
| 06:05 | spats to protect the shoes. Although the risk of a sodium leak or fire is minimal, there |
| 06:12 | is still the potential that such an incident could occur. With your help, however, we can |
| 06:16 | be prepared for such an incident and reduce the consequences. In the event of a sodium |
| 06:22 | fire, you should inform the control room and other personnel so that the area can be evacuated |
| 06:27 | immediately. Operations and maintenance personnel at FFTF are trained to respond in emergency |
| 06:33 | situations and fight any fire until the fire department arrives. |
| 06:39 | Another factor to consider is personal contact with sodium. Liquid sodium contact with your |
| 06:44 | skin poses two hazards. First, since your body is largely water, the sodium will interact |
| 06:51 | resulting in a caustic or chemical burn. |
| 06:56 | Second, because most sodium in FFTF will be above 300 degrees Fahrenheit, you could receive |
| 07:02 | a high temperature burn similar to the kind you would get from hot solder. |
| 07:08 | If liquid sodium comes into contact with your skin, you can reduce injury by following these |
| 07:13 | simple steps. |
| 07:14 | Brush the sodium off. |
| 07:17 | Immediately remove all clothing and get under a safety shower. |
| 07:21 | stay under the shower for at least 15 minutes. This will allow the remaining sodium to be |
| 07:27 | fully reacted with the shower water rather than with your skin. The reason you must remove |
| 07:33 | all clothing prior to entering the safety shower is to prevent any sodium which might |
| 07:37 | be trapped in the folds of the clothing or in the pockets from interacting with the water |
| 07:42 | in the shower. As you saw earlier the interaction of sodium with water could cause an explosion |
| 07:48 | leading to further injury. |
| 07:50 | In a sodium fire the white smoke produced is made up of sodium oxide. |
| 07:55 | It is very acrid and unpleasant. |
| 07:58 | But more important, this smoke can interact with the moisture in your lungs, |
| 08:02 | your eyes, or even with perspiration on your skin. |
| 08:07 | This interaction produces sodium hydroxide and again |
| 08:11 | this can result in a caustic burn. |
| 08:14 | If a sodium fire occurs, |
| 08:16 | Avoid contact or inhalation of the smoke. |
| 08:21 | As we have shown any contact with sodium, no matter how minor, |
| 08:25 | can produce caustic burns. |
| 08:28 | After washing the sodium off, go to first aid immediately. |
| 08:32 | Do not ignore the sodium contact because the sodium hydroxide burn will continue |
| 08:37 | to grow. |
| 08:38 | This effect can easily be counteracted by treatment at first aid. |
| 08:43 | We have had extensive experience in handling sodium. |
| 08:46 | at the high temperature sodium facility in the 300 area, |
| 08:50 | in the 200 area, and at EBR 2 in Idaho Falls. |
| 08:55 | We also have information on dealing effectively with sodium fires. |
| 09:00 | We're pleased to report there have been no major leaks or serious injuries. |
| 09:04 | This is a record we need your help in maintaining. |
| 09:08 | The actions you take in the event of a sodium leak or fire are simple and |
| 09:11 | effective. |
| 09:13 | With your help We will all continue to work in a safe and healthy environment at FFTF. |