Molten Salt Reactors (MSRs) are nuclear reactors that use a fluid fuel in the form of very hot fluoride or chloride salt instead of the solid fuel used in most reactors. Since the fuel salt is liquid, it can be both the fuel (producing the heat) and the coolant (transporting the heat to the power plant). There are many different types of MSRs, but the most talked about one is definitely the Liquid Fluoride Thorium Reactor (LFTR). This MSR has Thorium and Uranium dissolved in a fluoride salt and can get planet-scale amounts of energy out of our natural resources of Thorium minerals, much like a fast breeder can get large amounts of energy out of our Uranium minerals. There are also fast breeder fluoride MSRs that don’t use Th at all. And there are chloride salt based fast MSRs that are usually studied as nuclear waste-burners due to their extraordinary amount of very fast neutrons.
The benefits of MSRs are plentiful, hence their resilience as an interesting topic throughout reactor history. We break them down by topic here.
Sustainability is a measure of how efficiently a system can use natural resources. Most traditional reactors can only burn about 1% of the uranium on Earth. Many advanced reactors, including MSRs, can do much better. Here’s why MSRs are good in this regard.
Though economics are not truly known until a system is in commercial operation, there are reasons to think MSRs would have favorable low price.
The most important aspect of a nuclear reactor is safety. Here’s the good news for MSRs:
All those wonderful benefits can’t possibly come without a slew of problems. Lots of people promote these reactors without acknowledging the issues, but not us! A reactor concept has to stand on its two feet even in the face of disadvantages (and we think the MSR can do this). Let’s go through them.
The primary concern with MSRs is that the radioactive fission products can get everywhere. They are not in fuel pins surrounded by cladding, but are just in a big, sealed vat. You can put a double-layer containment around it, sure, but it is still challenging to keep them all accounted for. Where some of these fission products and actinides are radioactive, others have chemical effects that can eat away at the containment. The implications of this are many.
The main political barrier to MSRs is their perceived bomb-factory capabilities. If you talk to non-proliferation people, they will tell you that as soon as the (solid) fuel pins are cut open, a technology is considered proliferative. The problem with MSRs, then, is that the fuel is already completely cut open and melted. You’re halfway to a bomb already, they think. Here’s what they are worried about.
There are a few other concerns, but these probably have practical solutions
For MSRs to breed in a thermal spectrum, the lithium in the salt must be enriched to very pure Li-7. Li-6 is a strong neutron poison and becomes tritium, the pesky mobile radiation source. Also, Beryllium in Flibe is a controlled substance. It has some weapons applications and is a very dangerous material in terms of biological inhalation risks. In chloride salts, you must enrich to have pure Cl-37. Otherwise, Cl-35 has a strong (n,proton) threshold reaction that poisons the reactor. Also, the activation product Cl-36 is a long-lived, water soluble, hard beta emitter that complicates waste disposal. These enrichment needs increase the cost and complexity of MSR fuel cycles. Maybe we can find a more ideal salt someday.
There are more specific problems with more specific types of MSRs, but you get the general idea here. Basically, MSRs are underdeveloped and require a lot more research (especially in corrosion) before they can surely take off as the world’s fleet of power plants. Personally, we think (as did Alvin Weinberg and Edward Teller) that these reactors have a shining place in the mid-future. Right now, we have to keep studying them! Fortunately, much work is ongoing.
The first fluid fueled reactors were built during the Manhattan project. They were Aqueous Homogeneous Reactors (AHR), meaning they were solutions of uranium or plutonium in water. These small reactors were primarily used to study plutonium. Later (concurrently to MSR development), several AHR test reactors were built at Oak Ridge National Laboratory (these were the Homogeneous Reactor Experiments HRE-1 and HRE-2). Molten salt fuels were first conceived of in the late 1940s, when people began thinking of nuclear powered airplanes! The idea was to have very long range bombers in the air at all times. To heat air to high enough temperatures to provide thrust, such a nuclear reactor would need very high temperatures and very high power densities. The Aircraft Nuclear Propulsion program was a huge effort, and most of the early studies of molten salts were done under its direction. The first molten salt reactor, the Aircraft Reactor Experiment (ARE) operated in 1954 at ORNL with a Na-Zr-U salt for 100 hours. This reactor actually had fuel pumping through tubes in blocks of Beryllium. When inter-continental ballistic missiles came along, this program was promptly canceled.
After the cancellation of the ANP project, the people at ORNL wanted to use their MSR skills to build a commercial power plant. In 1956, ORNL director Alvin Weinberg hired a guy named MacPherson to form a group at ORNL to build such a thing. To be successful, they needed a fuel salt that absorbed very few neutrons, dissolved much uranium and thorium, was thermally stable, and was chemically compatible with structural materials. They decided the fluorides were best, but UF4 had a very high melting temperature (1035 C). Mixed with BeF2, the melting temperature became practical, but the viscosity was too high. Mixing in some LiF brought the viscosity down. Thus was born UF4-LiF-BeF2, now known as Flibe. Construction of a test reactor called the Molten Salt Reactor Experiment (MSRE) begin in 1962 using this salt (with a bit of ZrF4), and the plant began operation in 1966. In 1968, all the uranium was extracted and replaced with U-233, the fissile nuclide of the Thorium cycle. Thus, MSRE was the first reactor to operate on U-233. The reactor was shut down on schedule in 1969 as funding was set to go towards designing and building a bigger prototype MSR called the Molten Salt Breeder Reactor (MSBR).
But it would not be so! The Atomic Energy Commission (the ancestor of the Dept. of Energy) could not be convinced to put more money into the molten salt project. For one thing, they were already over budget on a very large and expensive fast-breeder project. Besides, there were some big problems at MSRE that some people were not convinced could be solved. ORNL director Alvin Weinberg put much energy into keeping the program going, but it was not destined to be. Funding was largely canceled and MSRs lost their momentum.
MSR work continued at a low budget. The ORNL experts came up with likely solutions to most of the problems raised at the MSRE. When proliferation concerns about the MSR were brought up in the 1980s, ORNL developed (on paper) something called the denatured MSR, or DMSR that was not fissile self-sufficient, but still offered favorable performance in comparison to traditional reactors. Others throughout the world worked on salt chemistry problems and developed many other designs, including some chloride salt fast breeder MSRs. Much later, in 2001, the MSR was chosen by the Generation IV forum as one of the 6 Gen-IV concepts. This jump-started work on MSRs and engineers and chemists have produced much good work on them since then.
The step-sister reactor of the MSR is the fluoride cooled high temperature reactor (FHR). These reactors have solid fuel in the form of TRISO particles (like the high temperature gas-cooled reactor), but rather than pumping high-pressure helium coolant through, they pump low-pressure liquid salt (usually Flibe) through. The idea here is to get the high-temperature and high-burnup benefits of the gas reactors without the risk of a depressurization accident. Salt coolant has incredible heat capacity (but low thermal conductivity), so it does a good job of handling accidents. These reactors are currently being studied by the DOE and many others (including the Chinese). Here is a PDF presentation by one of the PIs at MIT.
There is ongoing work in MSRs around the world. The Europeans are working on MOSART, the Japanese have FUJI, the Americans are focused on the FHR. Most recently, in 2011, the Chinese Academy of Science started a project in Shanghai to put substantial resources into MSR technology. There are 300-500 people on the project, with a budget in the hundreds of millions. Most of the work is on FHRs, but there is definitely MSR work as well. They are manufacturing Hastelloy-N, separating lithium, building salt loops, and building advanced modeling capabilities. That project is most likely the most exciting in MSRs since 1969. They plan on having both an experimental 2MW FHR and an experimental 2MW MSR operational by 2020.
Specific references coming soon. Almost all of this info was compiled from the incredible library of ORNL reports available online here. This stuff is pure gold.